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Most certificates will be issued by an intermediate authority that has been issued by a root authority. To make LCS support the certificate, you need to include root CA and intermediate CA in the PFX certificate for LCS. When certificate is imported to LCS, you can now download TMMS android APK from LCS.
To combine multiple PEM certificates, you just need to put the ASCII data from all of the certificates in a single file. Below is an example of this:
 
To be safe, work on your certificate starting from the root certificate and then, the intermediate certificate. Work your way down the chain to the root certificate.
 
-----BEGIN CERTIFICATE-----
MIIEKjCCAxKgAwIBAgIEOGPe+DANBgkqhkiG9w0BAQUFADCBtDEUMBIGA1UEChML
....
Omitted for brevity
....
u/8j72gZyxKTJ1wDLW8w0B62GqzeWvfRqqgnpv55gcR5mTNXuhKwqeBCbJPKVt7+
bYQLCIt+jerXmCHG8+c8eS9enNFMFY3h7CI3zJpDC5fcgJCNs2ebb0gIFVbPv/Er
fF6adulZkMV8gzURZVE=
-----END CERTIFICATE-----
-----BEGIN CERTIFICATE-----
MIIE9TCCA92gAwIBAgIETA6MOTANBgkqhkiG9w0BAQUFADCBtDEUMBIGA1UEChML
....
Omitted for brevity
....
mWEn7kVuxzn/9sWL4Mt8ih7VegcxKlJcOlAZOKlE+jyoz+95nWrZ5S6hjyko1+yq
wfsm5p9GJKaxB825DOgNghYAHZaS/KYIoA==
-----END CERTIFICATE-----
After combining the ASCII data into one file, verify validity of certificate chain for sslserver usage:
openssl verify -verbose -purpose sslserver -CAfile CAchain.pem name.pem
Combine the private key, certificate, and CA chain into a PFX:
openssl pkcs12 -export -out name.pfx -inkey name.<en|unen>crypted.priv.key -in name.pem -certfile CAchain.pem